to exhibit a negative thermal expansion (NTE). Nowadays, the materials science community is intrigued by the uncommon phenomenon that occurs in some types of materials, causing them to contract when heated, i.e. Typically, many materials exhibit positive thermal expansion (PTE).
Coherently intergrown NaMIm 3/NaIm (M = Mg, Mn) present colossal negative thermal expansion. Graphical abstractĬrystal structures of AMnIm 3 (A = Na, K) were determined. Such coherent coalescence of two materials opens the possibility for targeted design of zero thermal expansion materials. Such behaviour is caused by the coherent intergrowth of the coexisting phases which form a composite, a positive lattice mismatch and a tensile strain during the coexistence of NaMIm 3 (M = Mg and Mn) and NaIm or HT-NaIm. Extensive study of the thermal expansion behaviour revealed that the expansion of the bimetallic imidazolates does not proceed uniformly over the entire temperature range but rather abruptly changes from a colossal negative to a moderate positive volume expansion. Both the alkali metal cation and the Mn cations exhibit distorted octahedral coordination while each imidazolate is surrounded by two alkali metal and two manganese atoms. In the course of thermal evolution, crystal structures of two novel bimetallic imidazolates AMnIm 3 (A = Na, K) were solved using synchrotron radiation powder diffraction data. This work describes temperature-induced crystallization processes and reaction mechanisms occurring in the borohydride-imidazolate system.
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